Certainly for regular Jazz driving 99ron won't make any difference, but any extra additives may be beneficial although not explored below.
Petrol such as Tesco Momentum 99 is not '4% more potent' than 95ron (and consider diesel is around 20ron) like higher % alcohol would be; it will have a broadly similar hydrocarbon content across all grades. The octane rating is not an indicator of the energy content of the fuel, but a 'resistance to knock'. The extra rating means it can withstand a greater rise in temperature/pressure before uncontrolled self ignition, therefore it can be compressed to a higher ratio and you can get a bigger bang while avoiding premature ignition i.e. knock. We should never notice knock these days as it is closely monitored and the timing constantly advanced/retarded to keep it just at bay.
Higher octane fuel gives a performance advantage in engines designed specifically to run on it (e.g. Golf GTI +5hp), engines intended for standard fuel will never be able to realize it's potential.
Higher compression ratios generate greater thermal efficiencies from a 4-stroke engine and derive more energy for a given hydrocarbon content, that's why blowing in more air with a turbo at the beginning of the cycle gives a higher compression ratio and a greater fuel/air mixture and bang. The new generation of Honda 3 cylinder turbo engines are designed to get the most "activation energy" from each squirt of fuel by optimising the compression generated on each stroke to the maximum that the fuel mixture can sustain, the turbo is not for top end performance reasons.
Fuel seems to have a great placebo / marketing effect on its users, probably due to names such as "Shell V-Power Nitro+"
The trouble with habitual use of higher grades is when you diligently top-off the hire car to two clicks with it, before realising what a mug you are.
"Vauxhall spokesman Simon Hucknall says you’d be "wasting your money" by putting high octane performance fuel into most of its standard range of cars."
If I had an AMG C63 I'd fill it with 99ron, the Jazz gets 95.
As a technology demonstrator for Mobil*, we used to run a dual fuel LPG/petrol family car in the 70s controlled by a toggle switch on the dash, and the higher octane LPG (110ron) eliminated 'knock' which was a common issue back then, but not any better for standard driving due to a lower energy content.
*Father = chartered automotive engineer in ExxonMobil Special Products division. ExxonMobil (Esso) produce Tesco fuels.
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TG (oiled by Mobil 1 since first change)