I recently saw an elderly couple, on foot , putting petrol into a can . They had no idea what they were doing, and had probably never actually owned a car , but getting fuel for a new lawnmower etc. They left the fuel nozzle laying on the ground.

So as the OP may be completely new to actually buying petrol please excuse my stating the obvious. Make absolutely sure that you are buying petrol, not Diesel. Using the wrong grade of petrol will cost you more but its not a disaster. But if you realise you have put some diesel in by mistake do not drive the car. The fuel tank will need to be drained.
Different petrol companies have their own names for the various grades. With even the cheapest one hyped up by being called 'super extra' or some such. , with more expensive grades having another fancy name, Its not always obvious which is the better. And E10 'sounds' better than E5 Because its a bigger number, but its not.. And not all pumps help you out by displaying the price until you select a nozzle ..
But as others have said E10 from any supplier meets the specification for the car. Just look for the nozzle with an E10 sticker.