E5 is favourable especially if the car sits around unused. Esso is the best, as it has no ethanol in most of the UK.
From the Esso website:
"Although our pumps have E5 labels on them, our Synergy Supreme+ 99 is actually ethanol free (except, due to technical supply reasons, in Devon, Cornwall, North Wales, North England and Scotland). Legislation requires us to place these E5 labels on pumps that dispense unleaded petrol with ‘up to 5% ethanol’, including those that contain no ethanol, which is why we display them on our Synergy Supreme+ 99 pumps".