I used to find that on a humid day I would get misting on the outside of the windscreen when the air con was on and the system set to demist. At first I thought it was on the inside but the wipers would shift it!
Personally I have never found any of my cars particularly airtight. Draughts on a cold winter morning prove that.
In Scotland, setting your Climate Control to 16°C would see the heating on, for about 98% of the year!!